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Enantioselective gold( i )-catalyzed cyclization/intermolecular nucleophilic additions of 1,5-enyne derivatives

Abstract : An enantioselective Au(I)-catalyzed cyclization/nucleophilic addition process is developed, starting from 1,5-enyne substrates. A broad scope of ON N-and C-nucleophiles was introduced in order to provide the corresponding chiral cyclopentene derivatives in moderate to high yields and up to 96:4 enantiomeric ratio.
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https://hal.archives-ouvertes.fr/hal-03084435
Contributor : Arnaud Voituriez Connect in order to contact the contributor
Submitted on : Monday, December 21, 2020 - 10:39:44 AM
Last modification on : Saturday, July 3, 2021 - 12:14:28 AM

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Xu Han, Pascal Retailleau, Vincent Gandon, Arnaud Voituriez. Enantioselective gold( i )-catalyzed cyclization/intermolecular nucleophilic additions of 1,5-enyne derivatives. Chemical Communications, Royal Society of Chemistry, 2020, 56 (66), pp.9457-9460. ⟨10.1039/d0cc00914h⟩. ⟨hal-03084435⟩

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